THE UNDERGROUND (1997), starring Jeff Fahey.

Car chase #3:
The bad guy is in a Cadillac limousine. A motorcycle cop goes after them. But the situation is worse than it seems, so here comes Fahey! After managing to get on the limo, he fights with the bad guy, who is driving. However, a semitruck stalls in the middle of the road, and Fahey jumps out seconds before the limo crashes through the exploding trailer and flips over.